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Gay-Lussac’s Law is a direct mathematical relationship. This means there are two connected values and when one (either P or T) goes up, the other (either P or T) also increases. The constant K remains the same value. The mathematical form of Gay-Lussac’s Law is: Example #1: 10.0 L of a gas is found to exert 97.0 kPa at 25.0 °C. What would be the required temperature (in Celsius) to change the pressure to standard pressure? Solution: 1) Change 25.0 °C to 298.0 K and remember that standard pressure in kPa is 101.325. Insert values into the equation to get: 97.0 kPa 101.325 kPa––––––– = –––––––––298.0 K x x = 311.3 K 2) The question asks for Celsius, so you subtract 273 to get the final answer of 38.3°C. Notice that the volume never enters the problem. This is because the problem is asking about the relationship between pressure and temperature; the volume (as well as the moles) remains constant. Example #2: What is the new pressure (in atm) when a constant volume of gas is heated from 25.1 °C to 37.5 °C? The starting pressure is 755.0 mmHg. Solution: 1) Set it up and solve: 755.0 mmHg x–––––––––– = –––––––298.1 K 310.5 K x = 786.4 mmHg 2) Convert to atm:
You could have converted the 755.0 mmHg to atm first, if so desired. PRACTICE: If a gas in a closed container is pressurized from 15.0 atmospheres to 16.0 atmospheres and its original temperature was 25.0 °C, what would the final temperature of the gas be? 45.0 °C Recommended textbooks for you Chemistry Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste Publisher:Cengage Learning Chemistry Author:Raymond Chang Dr., Jason Overby Professor Publisher:McGraw-Hill Education Principles of Instrumental Analysis Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch Publisher:Cengage Learning Organic Chemistry Author:Janice Gorzynski Smith Dr. Publisher:McGraw-Hill Education Chemistry: Principles and Reactions Author:William L. Masterton, Cecile N. Hurley Publisher:Cengage Learning Elementary Principles of Chemical Processes, Bind... Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard Chemistry ISBN:9781305957404 Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste Publisher:Cengage Learning Chemistry ISBN:9781259911156 Author:Raymond Chang Dr., Jason Overby Professor Publisher:McGraw-Hill Education Principles of Instrumental Analysis ISBN:9781305577213 Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch Publisher:Cengage Learning Organic Chemistry ISBN:9780078021558 Author:Janice Gorzynski Smith Dr. Publisher:McGraw-Hill Education Chemistry: Principles and Reactions ISBN:9781305079373 Author:William L. Masterton, Cecile N. Hurley Publisher:Cengage Learning Elementary Principles of Chemical Processes, Bind... ISBN:9781118431221 Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard Publisher:WILEY |