The small balloon in a syringe for demonstrating Boyle’s law can be substituted with an air-containing, cut and knotted finger of an exam glove. The glove’s “finger balloon” is pushed into the open end of a 60-mL plastic syringe, and adhesive tape is attached to its opening to work as a removable stopper, Fig. 1. Decreasing the air pressure in a syringe is achieved by moving the plunger. The position of the plunger (decreased pressure, increased balloon volume) can be secured by making a hole in the plunger for a screw/nail, and the syringe can be handed to students for closer observation, Fig. 2. Taking off the tape will increase air pressure on the balloon, decreasing its volume, Fig. 3. It's interesting because people usually do the experiment in a closed syringe, increasing the air pressure by pushing down the plunger. In this case, by taking off the tape, air rushes inside, and the volume of the balloon decreases. A 60-mL syringe with a closed end (heated, softened and pressed with pliers) can also be used to demonstrate Charles’s law. If 40 mL of air is heated by a hair dryer, the volume of air will increase by 5-6 mL. At room temperature, the plunger of the syringe returns to the starting position — the volume decreases. The change will be faster if the syringe is cooled with running tap water or an ice bath with dissolved table salt. The volume changes are even faster if oil is applied on the rubber part of the plunger. In addition, there is an opportunity to discuss condensation and pressure change when the water vapour in hot air condenses to form droplets inside the syringe. 25th Dec 2019 @ 4 min read Boyle's law is a pressure versus volume relationship. The law was discovered by Robert Boyle in the 17th century. It states the pressure of a fixed amount of a gas is inversely proportional to its volume at a constant temperature. The law can be empirically proven. The article discusses an experimental method to verify the law using a syringe. Experiment: Sealed syringeThe experiment is very simple. It can be performed at home. When the tip of a syringe is sealed with a cap, the air inside the syringe is isolated from the atmosphere. This will fix the amount of the gas. The weights (books) are added upon the plunger of the syringe. It will push the plunger downwards; in other words, the air in the syringe is compressed. By recording the weights of the books added and the volume reading from the syringe, we can establish the pressure-volume relationship. ObjectiveTo verify Boyle's law and to plot the pressure-volume graph Materials
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ObservationThe initial weight (w0) is 92 g. The total weight is . The observation table is as follows:
CalculationThe pressure on the air inside the syringe is the pressure exerted by the weights plus atmospheric pressure. The pressure exerted by the weights is the force exerted by the weights divided the inner area of the syringe. Now, Force (Fw) is mass (Wi) times acceleration (a). Here, r is the inner radius of the syringe, which can be measured; r = 0.005 m. a is the acceleration due to gravity; a = 9.81 m s−2. For Wi = 92 g, Assume atmospheric pressure (Patm) as 101.325 kPa. Similarly, we can calculate the total pressure for the rest. The calculation table is as follows:
We have to plot the graph of Pi vs Vi and PiVi vs Vi. ResultsThe Pressure vs volume graph is as follows: Pressure vs volumeThe pressure-volume vs volume graph is as follows: Pressure-volume vs volumeConclusionThe PV curve from the above figure is satisfactory. As the pressure of the air increases, its volume decreases. The air obeys Boyle's law. Also, the product of pressure and volume approximately constant and its value is independent of volume or pressure. Also, check a laboratory method: To verify Boyle's law» Associated articles
Copy Article Cite "To Demonstrate Boyle's Law by Syringe Experiment" ChemistryGod, 25th Dec 2019, https://chemistrygod.com/demonstrate-boyle-lawThanks for your response!
Zephaniah Lapa Very helpful, Thankyou so much..
Henry Awesome! work, i like your examples, thank you sir. |